Biziuk, M. and Stocka, J. 2015. Multiresidue Methods for Determination of Currently Used Pesticides in Fruits and Vegetables Using QuEChERS Technique. International Journal of Environmental Science and Development, Vol. 6, No. 1.
Chai, L.K. and Elie, F. 2013. A rapid multi-residue method for pesticide residues determination in white and black pepper (Piper nigrum L.). Food Control, 32, 322-326.
Diaz, A. N., Sanchez, F.G., and Pareja, A.G. 1998. Resolution of Deltamethrin, Permethrin, and Cypermethrin Enantiomers by High-Performance Liquid Chromatography with Diode-Laser Polarimetric Detection. Journal of Chromatographic Science, Vol.36, 210-216.
Direktorat Jenderal Perkebunan. 2013. Statistik Perkebunan Indonesia, Lada. Jakarta: Direktorat Jenderal Perkebunan. Kementerian Pertanian.
Direktorat Jenderal Prasarana dan Sarana Pertanian. 2014. Pestisida Pertanian dan Kehutanan. Jakarta: Direktorat Jenderal Prasarana dan Sarana Pertanian. Kementerian Pertanian.
Ekaputri, R.A. 2013. Validasi Analisis Residu Pestisida Karbaril, Klorpirifos, dan Dimetoat dalam Buah Menggunakan Metode QuEChERS dan LC-MS/MS. Skripsi. Jakarta: Universitas Indonesia.
Eurachem. 1998. The fitness for purpose of analytical method: A laboratory guide to method validation and related topics. Diunduh di: https://www.eurachem.org/images/stories/Guides/pdf/MV_guide_1998_EN.pdf tanggal 9 November 2015.
European Standard. 2008. Foods of Plant Origin-Determination of Pesticide Residues Using GC-MS and/or LC-MS/MS Following Acetonitrile Extraction/Partitioning and Clean-up By Dispersive SPE-QuEChERS Method. EN 15662:2008. Brussels: European Committee for Standardization.
Frenich, A. G., Vidal, J. L. M., Montoro, E. P., and Gonzalez, R. R. 2008. High throughput determination of pesticide residues in food commodities by use of ultra-performance liquid chromatography-tandem mass spectrometry. Analytical and Bioanalytical Chemistry, 390, 947-959.
Halvorson, M., and Chambers, L. 2005. GPC clean-up of black pepper prior to analysis for organochlorine pesticides by GC/XSD. LC-GC North America, 23(6), 41-42.
Harmita. 2004. Petuinjuk Pelaksanaan Validasi Metode dan Cara Perhitungannya. Majalah Ilmu Kefarmasian, Vol. I, No.3, 117 – 135.
Haryono. 2014. Memperkuat Daya Saing Produk Pertanian. Jakarta: IAARD Press.
Mastovska, K., and Lehotay, S.J. 2004. Evaluation of Common Organic Solvents for Gas Chromatographic Analysis and Stability of Multiclass Pesticide Residues. Journal of Chromatography A, 1040: 259–272.
Narwanti, I., Sugiharto, E., dan Anwar, C. 2012. Residu Pestisida Piretroid pada Bawang Merah di Desa Srigading Kecamatan Sanden Kabupaten Bantul. Jurnal Ilmiah Kefarmasian, Vol. 2, No. 2, 119 – 128.
Pakvilai, N., Prapamontol, T., Thavornyutikarn, P., Mangklabruks, A., Chantara, C., Hongsibsong, S. and Santasup, C. 2015. A Simple and Sensitive GC-ECD Method for Detecting Synthetic Pyrethroid Insecticide Residues in Vegetable and Fruit Samples. Chiang Mai J. Sci. 42(1) : 196-207.
SANCO/10684/2009. 2009. Method validation and quality control procedures for pesticide residues analysis in food and feed. Diunduh di http://ec.europa.eu/food/plant/protection/resources/qualcontrol_en.pdf tanggal 9 November 2015.
Wiratno, Taniwiryono, D., Brink, P.J.V., Rietjens, I.M.C.M., and Murk, A.J. 2007. A Case Study on Bangka Island, Indonesia on the Habits and Consequences of Pesticide Use in Pepper Plantations. Environ Toxicol. 22(4) : 405-14.
Willard, H.H., Merritt, Jr., Dean, J.A., and Settle, Jr., F.A. 1988. Instrumental Method of Analysis. 7th Edition. California : Wadsworth Publishing Co.
Zhang, Y., Hu, D., Zeng, S., Lu, P., Zhang, K., Chen, L., and Song, B. 2015. Multiresidue determination of pyrethroid pesticide residues in pepper through a modified QuEChERS method and gas chromatography with electron capture detection, Biomed. Chromatogr. 2015.
- Abstract viewed - 855 times
- PDF downloaded - 2275 times
Affiliations
Bayu Refindra Fitriadi
Balai Besar Perbenihan dan Proteksi Tanaman Perkebunan (BBPPTP) Surabaya
Ayutia Ciptaningtyas Putri
Balai Besar Perbenihan dan Proteksi Tanaman Perkebunan (BBPPTP) Surabaya
How to Cite
PENENTUAN RESIDU PESTISIDA DELTAMETRIN DAN λ-SIHALOTRIN PADA LADA (Piper nigrum L.) MENGGUNAKAN METODE QuEChERS
Abstract
The use of pesticides in agriculture especially pepper concern of residue accumulation, which may remain in the food and agricultural environment causing human health and damaging ecological balance. Beside that, pepper with high residue pesticide will be rejected by export destination countries. This study reported is based on the determination of deltamethrin and λ-cyhalothrin residue in pepper. Pepper was taken from supermarkets and pepper exporters in East Java. The pesticide residues were extracted and cleaned-up with optimalized QuEChERS method and determination was carried out on GC-ECD. Deltamethrin and λ-cyhalothrin respons have linear correlation with the concentrations at the range of 0.01 to 1.00 µg/mL (determination coefficient, r2, was 0.9993 and 0.9950). Detection and quantitation limits for deltamethrin were 0.020 µg/mL and 0.067 µg/mL, respectively, while detection and quantitation limits for λ-cyhalothrin  were 0.090 µg/mL and 0.301 µg/mL, respectively. Recoveries of these residues are between 99-143%. All pepper samples were tested, was undetected contain residues of λ-cyhalothrin and deltamethrin.