The Effect of Beeswax and Glycerol Addition on the Performance of Bioplastic Film Made of Konjac Glucomannan

Suharno Rusdi, Imam Nurrahman, Wildan Nur Rizki, Achmad Chafidz

Abstract

In this study, bioplastics made of Konjac glucomannan have been successfully prepared via film casting method. The effects of addition of beeswax content (i.e. of 0%, 0.5%, and 1%,), as well as glycerol content (i.e. 0.5%, 1%, and 1.5%) on the properties of the bioplastics have been investigated. The bioplastics produced have been characterized for their tensile strength, percent elongation, swelling degree, and biodegradability. The results of this study, showed that most of the bioplastic samples have weight loss of about 95% after the drying process as well as the finished film. The addition of beeswax and glycerol concentrations also increased tensile strength and percent elongation of the bioplastics. The highest value of tensile strength occurred at bioplastic film with a concentration of 1.5% beeswax and 1% glycerol (i.e. Sample C3) with a value of approximately 3.5 MPa. Whereas, the highest percent elongation value occurred at bioplastic film with a concentration of 1.5% beeswax and 1% glycerol (i.e. Sample C3) with a value of approximately 23.29%. These tensile and percent elongation values were higher or comparable to other bioplastic samples made from starch of different raw materials reported by literatures. In the other hand, the addition of beeswax and glycerol decreased the degree of swelling. The degree of swelling for all the bioplastic film samples were in the range of 316.77 – 481%.

Keywords

bioplastics, biodegradable, konjac glucomannan, beeswax, glycerol

Full Text:

PDF

References

Abdullah, A. H. D., Anti, K. F., Oceu, D. P., Putri, P. P. A. 2019. Fabrication and Characterization of Poly Lactic Acid (PLA)-Starch Based Bioplastic Composites. IOP Conference Series: Materials Science and Engineering. 553:12052.

Amin, Md. R., Chowdhury, M. A., Kowser, Md. A. 2019. Characterization and Performance Analysis of Composite Bioplastics Synthesized Using Titanium Dioxide Nanoparticles with Corn Starch. Heliyon. 5 (8): e02009.

Anugrahwidya, R., Armynah, B., Tahir, D. 2021. Bioplastics Starch-Based with Additional Fiber and Nanoparticle: Characteristics and Biodegradation Performance: A ReviewBioplastics Starch-Based with Additional Fiber and Nanoparticle: Characteristics and Biodegradation Performance: A Review. Journal of Polymers and the Environment. 29(11): 3459–76.

Atiwesh, G., Mikhael, A., Parrish, C. C., Banoub, J., Le, T. T. 2021. Environmental Impact of Bioplastic Use: A Review. Heliyon, 7 (9): e07918.

Behera, L., Mohanta, M., Thirugnanam, A. 2022. Intensification of Yam-Starch Based Biodegradable Bioplastic Film with Bentonite for Food Packaging Application. Environmental Technology & Innovation. 25: 102180.

Cornelia, M., Syarief, R., Effendi, H., Nurtama, B. 2013. Pemanfaatan Pati Biji Durian (Durio Zibethinus Murr.) Dan Pati Sagu (Metroxylon Sp.) Dalam Pembuatan Bioplastik. Jurnal Kimia Dan Kemasan. 35 (1): 20–29.

Gabriel, A. A., Solikhah, A. F., Rahmawati, A. Y. 2021. Tensile Strength and Elongation Testing for Starch-Based Bioplastics Using Melt Intercalation Method: A Review. Journal of Physics: Conference Series. 1858: 12028.

Garcia, M. A. V. T., Garcia, C. F., Faraco, A. A. G. 2020. Pharmaceutical and Biomedical Applications of Native and Modified Starch: A Review. Starch‐Stärke. 72(7–8): 1900270.

Gujar, S., Pandel, B., Jethoo, A. S. 2014. Effect of Plasticizer on Mechanical and Moisture Absorption Properties of Eco-Friendly Corn Starch-Based Bioplastic. Nature Environment and Pollution Technology. 13(2): 425.

Hamid, L., Elhady, S., Abdelkareem, A., Fahim, I. 2022. Fabricating Starch-Based Bioplastic Reinforced with Bagasse for Food Packaging. Circular Economy and Sustainability. 2(3): 1065–76.

Ismail, N. A., Tahir, S. M., Yahya, N., Wahid, M. F. A., Khairuddin, N. E., Hashim, I., Rosli, N., Abdullah, M. A. 2016. “Synthesis and Characterization of Biodegradable Starch-Based Bioplastics.” In Materials Science Forum, 846:673–78. Trans Tech Publ.

Moshood, T. D., Nawanir, G., Mahmud, F., Mohamad, F., Ahmad, M. H., Ghani, A. A. 2022. Sustainability of Biodegradable Plastics: New Problem or Solution to Solve the Global Plastic Pollution?. Current Research in Green and Sustainable Chemistry. 5: 100273.

Oluwasina, O. O., Akinyele, B. P., Olusegun, S. J., Oluwasina, O. O., Mohallem, N. D. S. 2021. Evaluation of the Effects of Additives on the Properties of Starch-Based Bioplastic Film. SN Applied Sciences. 3 (4): 1–12.

Oluwasina, O. O., Olaleye, F. K., Olusegun, S. J., Oluwasina, O. O., Mohallem, N. D. S. 2019. Influence of Oxidized Starch on Physicomechanical, Thermal Properties, and Atomic Force Micrographs of Cassava Starch Bioplastic Film. International Journal of Biological Macromolecules. 135: 282–93.

Özdamar, E. G., Murat, A. 2018. Rethinking Sustainability: A Research on Starch Based Bioplastic. Journal of Sustainable Construction Materials and Technologies. 3(3): 249–60.

Pfister, B., Zeeman, S. C. 2016. Formation of Starch in Plant Cells. Cellular and Molecular Life Sciences. 73(14): 2781–2807.

Santana, R. F., Bonomo, R. C. F., Gandolfi, O. R. R., Rodrigues, L. B., Santos, L. S., Pires, A. C. S., Oliveira, C. P., Fontan, R. C. I., Veloso, C. M. 2018. Characterization of Starch-Based Bioplastics from Jackfruit Seed Plasticized with Glycerol. Journal of Food Science and Technology. 55(1): 278–86.

Vadori, R., Mohanty, A. K., Misra, M. 2013. The Effect of Mold Temperature on the Performance of Injection Molded Poly (Lactic Acid)‐Based Bioplastic. Macromolecular Materials and Engineering. 298(9): 981–90.

Zoungranan, Y., Lynda, E. , Dobi-Brice, K. K., Tchirioua, E., Bakary, C., Yannick, D. D. 2020. Influence of Natural Factors on the Biodegradation of Simple and Composite Bioplastics Based on Cassava Starch and Corn Starch. Journal of Environmental Chemical Engineering. 8(5): 104396.

Refbacks

  • There are currently no refbacks.