Isothermal Adsorption of Used Cooking Oil Purification Using Avocado Seed Adsorbent

Harianingsih Harianingsih, Wara Dyah Pita Rengga, Athiya Rihadatul 'Aisy Qothrun Nada, Rizki Ria Ramadhani, Alifyan Syauqi, Retno Wulandari

Abstract

High consumption of cooking oil has an impact on the availability of used cooking oil. Used cooking oil can cause pollution if the processing is not sound. So we need an alternative as a solution for handling cooking oil waste. Adsorption using avocado seed adsorbent is the choice because the morphological structure and other characteristics meet the specifications for the adsorption of used cooking oil. This study aimed to determine the acid number, viscosity, density and isothermal adsorption from avocado seeds as an adsorbent in used cooking oil. The method used was by varying the adsorbent doses of 100, 200 and 300 mg    L-1 with contact times of 30, 60, 90, 120 and 150 minutes. Adsorption was carried out at a temperature of 70oC and a stirring speed of 200 rpm. The results obtained for the acid numbers at various adsorbent doses at 150 minutes reached 6.22, 4.98 and 3.12 mg KOH      g-1. Viscosity at different adsorbents reached 54.2, 46.23 and 45.44 mm2 s-1, while the density reached 898.92, 897.17 and 896.55 kg m-3. Langmuir isothermal adsorption obtained R2 value in the equation reached 0.9365 and Freundlich reached 0.9496, so the Freundlich equation model is more recommended for use in the adsorption process because the regression value is close to 1.

Keywords

: adsorbent, avocado seed, Freundlich, isothermal adsorption, Langmuir, used cooking oil

Full Text:

PDF

References

Bangar, S. P., Dunno, K., Dhull, S. B., Siroha, A. K., Changan, S., Maqsood, S., Rusu, A. V. 2022. Avocado seed discoveries: Chemical composition, biological properties, and industrial food applications. Food Chemistry: X. 16: 100507.

Cárdenas, J., Orjuela, A., Sánchez, D. L., Narváez, P. C., Katryniok, B., Clark, J. 2021. Pre-treatment of used cooking oils for the production of green chemicals: A review. Journal of Cleaner Production. 289: 125129.

Cheikhyoussef, N., Cheikhyoussef, A. 2022. Avocado (Persea Americana) Wastes: Chemical Composition, Biological Activities and Industrial Applications. In Ramadan, M. F., Farag, M. A. (eds) Mediterranean Fruits Bio-wastes. Springer, Cham. 699-719.

Das, A., Bar, N., Das, S. 2020. Pb (II) adsorption from aqueous solution by nutshells, green adsorbent: adsorption studies, regeneration studies, scale-up design, its effect on biological indicator and MLR modeling. Journal of Colloid and Interface Science. 580: 245-255.

García-Vargas, M., Contreras, M., Castro, E. 2020. Avocado-derived biomass as a source of bioenergy and bioproducts. Applied Sciences. 10(22): 8195.

Irmanelly, I., Affrizal, A., Hierdawati, T., Amrizal, Dani, R. 2022. Cooking Oil Scarcity Phenomenon in Indonesia in 2022. International Journal of Artificial Intelligence Research. 6(1): 1-3.

Işık, B., Uğraşkan, V. 2021. Adsorption of methylene blue on sodium alginate–flax seed ash beads: Isotherm, kinetic and thermodynamic studies. International Journal of Biological Macromolecules. 167: 1156-1167.

Majd, M. Kordzadeh-Kermani, V., Ghalandari, V., Askari, A., Sillanpää, M. 2021. Adsorption isotherm models: A comprehensive and systematic review. Science of The Total Environment. 812: 151334.

Miskah, S., Aprianti, T., Putri, S. S., Haryanti, S. 2018. Purifikasi minyak jelantah menggunakan karbon aktif dari kulit durian. Jurnal Teknik Kimia. 24(1): 32-39.

Mohamed, E. M., Ghada, F. E. S., Ghada, A. I. Almaza, A. E., 2022. Effective removal of hexavalent chromium from water by sustainable nano-scaled waste avocado seeds: adsorption isotherm, thermodynamics, kinetics, and error function. Biomass Conversion and Biorefinery.

Muluh, S., Ghogomu, J., Ajifack, D. 2017. Adsorption of phenol from aqueous solution by avocado seed activated carbon: Equilibrium, kinetic, and full factorial design analysis.. International Journal of Advanced Engineering Research and Technology. 5(8): 610-620.

Rodriguez, M., Romaní, A., Eibes, G., Garrote, G., Gullón, B., del Río, P. G. 2022. Potential and prospects for utilization of avocado by-products in integrated biorefineries. Bioresource Technology. 364: 128034.

Solangi, N., Kumar, J., Mazari, S. A., Ahmed, S., Fatima, N., Mubarak, N. M. 2021. Development of fruit waste derived bio-adsorbents for wastewater treatment: A review. Journal of Hazardous Materials, 416: 125848.

Tefera, N., Mulualem, Y., Jernal, Fito, J. 2020. Adsorption of fluoride from aqueous solution and groundwater onto activated carbon of avocado seeds. Water Conservation Science and Engineering. 5(3): 187-197.

Waluyo, U., Ramadhani, A., Suryadinata, A., Cundari, L. 2020. penjernihan minyak goreng bekas menggunakan berbagai jenis adsorben alami. Jurnal Teknik Kimia. 26(2): 70-79.

Refbacks

  • There are currently no refbacks.