Das, N. S., 2011. Zeolite Synthesis and Its Application as Adsorbent. India : Thapar University
Endrias, H., Kasmui. dan Prasetya, A. T., 2013. Pengaruh Rasio Si/Al, Kation dan Template Organik terhadap Ukuran Rongga Zeolit ZSM-5. Indo. J. Chem Sci 1. (2). Tersedia di http://journal.unnes.ac.id/sju/index.php/ijcs
Faghihian, H. dan Godazandeha, N., 2009. Synthesis of Nano Crystalline Zeolite Y from Bentonite. Journal of Porous Material 16:331–335.
Feng , H., Li, C. dan Shan, H., 2009. In-situ Synthesis and Catalytic Activity of ZSM-5 Zeolite. Applied Clay Science, 42: 439–445.
Gunawan, B. dan Azhari, C., D., 2010. Karakterisasi Spektrofotometri IR dan Scanning Electron Microscopy (SEM) Sensor Gas dari Bahan Polimer Poly Ethelyn Glycol (PEG). ISSN : 1979-6870.
Harjanti, R. S., 2008. Pemungutan Kurkumin dari Kunyit (Curcuma domestica val.) dan Pemakaiannya Sebagai Indikator Analisis Volumetri. Jurnal Rekayasa Proses, 2 (1).
Hashemian. S., Hosseini, S.H., Salehifar, H. dan Salari, K., 2013. Adsorption of Fe(III) from Aqueous Solution by Linde Type-A Zeolite. American Journal of Analytical Chemistry, 4: 123-126.
He, B.B., 2009. Two-Dimensional X-Ray Diffraction. Published by John Wiley & Sons, Inc., Hoboken, New Jersey.
Hui, K.S. dan Chao, C.Y.H., 2006. Pure Single Phase Hgh Crystalline Chamfered Edge Zeolite 4A Synthesized from COal Fly Ash for Use a Builder Detergens, Journal of Hazardous Materials, 137 (1): 401-409.
Ika, D., 2009. Alat Otomatisasi Pengukur Kadar Vitamin C dengan Metode Titrasi Asam Basa. Jurnal Neutrino, 1 (2).
Jalaluddin. dan Jamaluddin., 2005. Pemanfaatan Kaolin sebagai Bahan Baku Pembuatan Alumunium Sulfat dengan Metode Adsorps. Jurnal Sistem Teknik Industri : 6 (5).
Jamaludin, A. dan Adiantoro, D., 2012. Analisis Kerusakan X-Ray Fluorescence (XRF). Pusat Teknologi Bahan Bakar Nuklir – BATAN : ISSN 1979-2409, No : 09-10.
Jumaeri, Astuti, W. dan Lestari, W.T.P., 2007. Preparasi dan Karakterisasi Zeolit Dari Abu Layang Batubara Secara Alkali Hidrotermal. Reaktor, 11: 38-44.
Ma, Y., Yan, C., Alshameri, A., Qiu, X., Zhou, C. dan Li, D., 2013. Synthesis and Characterization of 13X Zeolite from Low-grade Natural Kaolin. http://dx.doi.org/10.1016/j.apt.2013.08.002.
Madejová, J., 2003. FTIR techniques in clay mineral studies. Vibrational Spectroscopy. 31 : 1–10
Molina, A. dan Poole, C., 2004. A comparative study using two methods to produce zeolites from fly ash. Journal of Minerals Engineering. 17:167–173.
Muller, J.C. M., Hakvoort, G. dan Jansen., J.C., 1998. DSC and TG Study of Water Adsorption and Desorption on Zeolite Na-A. Journal of Thermal Analysis, 53: 258-261.
Nur, H., 2001. Direct Synthesis of NaA Zeolite from Rice Husk Ash and Carbonaceous Rice Husk Ash. Indonesian Journal of Agricultural Sciences, 1: 40-45.
Ojha, K., Pradhan, N.C. dan Samanta, A.N., 2004. Zeolite from Fly Ash: Synthesis and Characterisation. Indian of Academic Science, 27 (6): 555-564.
Prasetyoko, D., Saequ. dan Hartanto, D., 2010. Kristalisasi Zeolit A Murni Dari Abu Layang Batubara Paiton Menggunakan Metode Fusi Alkali : Pengaruh Waktu Hidrotermal. SN-KPK II
Purnomo, B. R. B. dan Fredinansyah, R., 2012. Pengembangan Metode Kalsinasi Pada Aktivasi Alkali Digestion Untuk Sintesa Zeolit Alam Bandung. Surabaya : Institut Teknologi Sepuluh Nopember Surabaya.
Purnomo, C.W., Salim, C. dan Hinode, F., 2012. Synthesis of Pure Na–X and Na–A Zeolite from Bagasse Fly Ash. Journal of Microporous and Mesoporous Materials 162: 6–13.
Reyes, C. A. R., Williams, C. D. dan Alarcon, O. M. C., 2013. Nucleation and Growth Process of Sodalite and Cancrinite from Kaolinite-rich Clay under Low-temperature Hydrothermal Conditions. Materials Research. 16(2): 424-438.
Reyes, C. A. R., Williams, C. D. dan Alarcon, O. M. C., 2010. Synthesis of zeolite LTA from thermally treated kaolinite. Rev. Fac. Ing. Univ. Antioquia N.53 pp. 30-41. Junio.
Rohaeti, Eli. 2002. Karakterisasi Biodegradasi Polimer. Jurdik Kimia FMIPA UNY : Yogyakarta.
Samadhi, T. W., Subagjo, Lismana, K. R. dan Fuadi, K., 2011. Synthesis of ï§-Al2O3 Catalyst Support from Kaolin of Indonesian Origin. ITB. Journal of Engineering Sciences. 43 (2):113-126.
Saputra, R., 2006. Kajian Modifikasi dan Karakterisasi Zeolit Alam dari Berbagai Negara. Jurnal Hibah Bersaing. 1 (3).
Schubert, U. dan Husing, N., 2000. Synthesis of Inorganic Materials. Federal Republic of Germany: Willey-VCH.
Septawendar, R., Rasma, A., Sutardi, S. dan Ramadhan, A., 2013. Preparation of Nano α-Al2O3 from Kaolin Belitung by Liquid Polish Milling. Journal of Ceramic Processing Research. 14 (1): 35-40.
Septiyana, D. dan Prasetyoko, D., 2012. Sintesis ZSM-5 Berbahan Dasar Kaolin
Menggunakan Metode Hidrotermal. Jurnal Sains dan Seni. 1 (1):1-4.
Smart, L. dan Moore, E., 1993. Solid State Chemistry : An Introduction, 1st edition. Chapman and Hall University and Proffesonal Division, London.
Syahfitri, W. Y. N., Kurniawati, S., Adventini, N. dan Lestiani, D. D., 2013. Evaluasi Penerapan Energi Dispersive X-Ray Fluorescence (ED-XRF) untuk Analisis Coal Fly Ash. Prosiding Seminar Nasional Sains dan Teknologi Nuklir. Bandung: PTNBR BATAN.
Treacy, M.M.J. dan J.B. Higgins., 2001. Collection of Simulated XRD Powder Patterns for Zeolites. Elsevier.
Wajima, T. dan Ikegami, Y., 2009. Synthesis of Crystalline Zeolite 13X from Waste Porcelain Using Alkali Fusion. Journal of Ceramics International 35: 2983–2986.
Wajima, T., Yosshizuka, K., Hirai, T. dan Ikegami, Y., 2008. Synthesis of Zeolite X from Waste Sandstone Cake Using Alkali Fusion Method. Materials Transactions, 49 (3): 612-618.
Wang, J.Q., Huang, Y.X., Pan, Y. dan Mi, J.X., 2014. Hydrothermal Synthesis of High Purity Zeolite A from Natural Kaolin without Calcination. http://dx.doi.org/10.1016/j.micromeso.2014.08.002.
Warren, B.E., 1969 . X-ray Diffraction. Dover Publication INC : New York
Widiawati., 2005. Sintesis Zeolit dari Abu Ketel Asal Pg. Tasik Madu: Ragam Zeolit pada Berbagai Konsentrasi Natrium Aluminat. Skripsi. Surakarta : Universitas Negeri Sebelas Maret.
Widiastuti, N. dan Rella, S, P., 2013. Sintesis dan Karakterisasi Zeolit A Berpendukung Material Serat dengan Variasi Jumlah Material Pendukung. Jurnal Sains Dan Seni POMITS. 2 (1):1-5.
Wongwiwattana, J., 2002. Synthesis and Kinetic Study of Zeolite Na-A From Thai Kaolin. Thailand : Suranaree University of Technology.
Yunita, I., 2008. Pengaruh Waktu Reaksi Pada Sintesis Zeolit Dari Abu Sekam Padi Serta Aplikasinya Sebagai Penukar Ion. Tugas Akhir 2. Semarang: Jurusan Kimia FMIPA UNNES.
Zhang, X., Tang, D., Zhang, M. dan Yang, R., 2013. Synthesis Of Nax Zeolite: Influence Of Crystallization Time, Temperature And Batch Molar Ratio SiO2/Al2O3 On The Particulate Properties Of Zeolite Crystals. Powder Technology 235: 322–328
Zhao, Y., Zhang, B., Zhang, X., Liu, J. dan Chen, R., 2010. Ammonium Removal from Aquoeous Solution by Zeolite X Synthesized from Halloysite Mineral. Water Science & Technology. 62 (4): 937-946.
Zhely, M. N. H. dan Widiastuti N., 2012. Sintesis Zeolit X-karbon dari Abu Dasar Batubara dan Karakterisasinya sebagai Material Penyimpan Hidrogen. Prosiding KIMIA FMIPA – ITS.
Zhou, W. dan Wang, Z.L., 2006. Scanning Microscopy for Nanotechnology. Library of Congress Control Number: 2006925865.
Zhou, Z., Jin, G., Liu, H., Wu, J. dan Mei, J., 2014. Crystallization Mechanism of Zeolite A from Coal Kaolin Using A Two-step Method. Applied Clay Science 97–98: 110–114.
Endrias, H., Kasmui. dan Prasetya, A. T., 2013. Pengaruh Rasio Si/Al, Kation dan Template Organik terhadap Ukuran Rongga Zeolit ZSM-5. Indo. J. Chem Sci 1. (2). Tersedia di http://journal.unnes.ac.id/sju/index.php/ijcs
Faghihian, H. dan Godazandeha, N., 2009. Synthesis of Nano Crystalline Zeolite Y from Bentonite. Journal of Porous Material 16:331–335.
Feng , H., Li, C. dan Shan, H., 2009. In-situ Synthesis and Catalytic Activity of ZSM-5 Zeolite. Applied Clay Science, 42: 439–445.
Gunawan, B. dan Azhari, C., D., 2010. Karakterisasi Spektrofotometri IR dan Scanning Electron Microscopy (SEM) Sensor Gas dari Bahan Polimer Poly Ethelyn Glycol (PEG). ISSN : 1979-6870.
Harjanti, R. S., 2008. Pemungutan Kurkumin dari Kunyit (Curcuma domestica val.) dan Pemakaiannya Sebagai Indikator Analisis Volumetri. Jurnal Rekayasa Proses, 2 (1).
Hashemian. S., Hosseini, S.H., Salehifar, H. dan Salari, K., 2013. Adsorption of Fe(III) from Aqueous Solution by Linde Type-A Zeolite. American Journal of Analytical Chemistry, 4: 123-126.
He, B.B., 2009. Two-Dimensional X-Ray Diffraction. Published by John Wiley & Sons, Inc., Hoboken, New Jersey.
Hui, K.S. dan Chao, C.Y.H., 2006. Pure Single Phase Hgh Crystalline Chamfered Edge Zeolite 4A Synthesized from COal Fly Ash for Use a Builder Detergens, Journal of Hazardous Materials, 137 (1): 401-409.
Ika, D., 2009. Alat Otomatisasi Pengukur Kadar Vitamin C dengan Metode Titrasi Asam Basa. Jurnal Neutrino, 1 (2).
Jalaluddin. dan Jamaluddin., 2005. Pemanfaatan Kaolin sebagai Bahan Baku Pembuatan Alumunium Sulfat dengan Metode Adsorps. Jurnal Sistem Teknik Industri : 6 (5).
Jamaludin, A. dan Adiantoro, D., 2012. Analisis Kerusakan X-Ray Fluorescence (XRF). Pusat Teknologi Bahan Bakar Nuklir – BATAN : ISSN 1979-2409, No : 09-10.
Jumaeri, Astuti, W. dan Lestari, W.T.P., 2007. Preparasi dan Karakterisasi Zeolit Dari Abu Layang Batubara Secara Alkali Hidrotermal. Reaktor, 11: 38-44.
Ma, Y., Yan, C., Alshameri, A., Qiu, X., Zhou, C. dan Li, D., 2013. Synthesis and Characterization of 13X Zeolite from Low-grade Natural Kaolin. http://dx.doi.org/10.1016/j.apt.2013.08.002.
Madejová, J., 2003. FTIR techniques in clay mineral studies. Vibrational Spectroscopy. 31 : 1–10
Molina, A. dan Poole, C., 2004. A comparative study using two methods to produce zeolites from fly ash. Journal of Minerals Engineering. 17:167–173.
Muller, J.C. M., Hakvoort, G. dan Jansen., J.C., 1998. DSC and TG Study of Water Adsorption and Desorption on Zeolite Na-A. Journal of Thermal Analysis, 53: 258-261.
Nur, H., 2001. Direct Synthesis of NaA Zeolite from Rice Husk Ash and Carbonaceous Rice Husk Ash. Indonesian Journal of Agricultural Sciences, 1: 40-45.
Ojha, K., Pradhan, N.C. dan Samanta, A.N., 2004. Zeolite from Fly Ash: Synthesis and Characterisation. Indian of Academic Science, 27 (6): 555-564.
Prasetyoko, D., Saequ. dan Hartanto, D., 2010. Kristalisasi Zeolit A Murni Dari Abu Layang Batubara Paiton Menggunakan Metode Fusi Alkali : Pengaruh Waktu Hidrotermal. SN-KPK II
Purnomo, B. R. B. dan Fredinansyah, R., 2012. Pengembangan Metode Kalsinasi Pada Aktivasi Alkali Digestion Untuk Sintesa Zeolit Alam Bandung. Surabaya : Institut Teknologi Sepuluh Nopember Surabaya.
Purnomo, C.W., Salim, C. dan Hinode, F., 2012. Synthesis of Pure Na–X and Na–A Zeolite from Bagasse Fly Ash. Journal of Microporous and Mesoporous Materials 162: 6–13.
Reyes, C. A. R., Williams, C. D. dan Alarcon, O. M. C., 2013. Nucleation and Growth Process of Sodalite and Cancrinite from Kaolinite-rich Clay under Low-temperature Hydrothermal Conditions. Materials Research. 16(2): 424-438.
Reyes, C. A. R., Williams, C. D. dan Alarcon, O. M. C., 2010. Synthesis of zeolite LTA from thermally treated kaolinite. Rev. Fac. Ing. Univ. Antioquia N.53 pp. 30-41. Junio.
Rohaeti, Eli. 2002. Karakterisasi Biodegradasi Polimer. Jurdik Kimia FMIPA UNY : Yogyakarta.
Samadhi, T. W., Subagjo, Lismana, K. R. dan Fuadi, K., 2011. Synthesis of ï§-Al2O3 Catalyst Support from Kaolin of Indonesian Origin. ITB. Journal of Engineering Sciences. 43 (2):113-126.
Saputra, R., 2006. Kajian Modifikasi dan Karakterisasi Zeolit Alam dari Berbagai Negara. Jurnal Hibah Bersaing. 1 (3).
Schubert, U. dan Husing, N., 2000. Synthesis of Inorganic Materials. Federal Republic of Germany: Willey-VCH.
Septawendar, R., Rasma, A., Sutardi, S. dan Ramadhan, A., 2013. Preparation of Nano α-Al2O3 from Kaolin Belitung by Liquid Polish Milling. Journal of Ceramic Processing Research. 14 (1): 35-40.
Septiyana, D. dan Prasetyoko, D., 2012. Sintesis ZSM-5 Berbahan Dasar Kaolin
Menggunakan Metode Hidrotermal. Jurnal Sains dan Seni. 1 (1):1-4.
Smart, L. dan Moore, E., 1993. Solid State Chemistry : An Introduction, 1st edition. Chapman and Hall University and Proffesonal Division, London.
Syahfitri, W. Y. N., Kurniawati, S., Adventini, N. dan Lestiani, D. D., 2013. Evaluasi Penerapan Energi Dispersive X-Ray Fluorescence (ED-XRF) untuk Analisis Coal Fly Ash. Prosiding Seminar Nasional Sains dan Teknologi Nuklir. Bandung: PTNBR BATAN.
Treacy, M.M.J. dan J.B. Higgins., 2001. Collection of Simulated XRD Powder Patterns for Zeolites. Elsevier.
Wajima, T. dan Ikegami, Y., 2009. Synthesis of Crystalline Zeolite 13X from Waste Porcelain Using Alkali Fusion. Journal of Ceramics International 35: 2983–2986.
Wajima, T., Yosshizuka, K., Hirai, T. dan Ikegami, Y., 2008. Synthesis of Zeolite X from Waste Sandstone Cake Using Alkali Fusion Method. Materials Transactions, 49 (3): 612-618.
Wang, J.Q., Huang, Y.X., Pan, Y. dan Mi, J.X., 2014. Hydrothermal Synthesis of High Purity Zeolite A from Natural Kaolin without Calcination. http://dx.doi.org/10.1016/j.micromeso.2014.08.002.
Warren, B.E., 1969 . X-ray Diffraction. Dover Publication INC : New York
Widiawati., 2005. Sintesis Zeolit dari Abu Ketel Asal Pg. Tasik Madu: Ragam Zeolit pada Berbagai Konsentrasi Natrium Aluminat. Skripsi. Surakarta : Universitas Negeri Sebelas Maret.
Widiastuti, N. dan Rella, S, P., 2013. Sintesis dan Karakterisasi Zeolit A Berpendukung Material Serat dengan Variasi Jumlah Material Pendukung. Jurnal Sains Dan Seni POMITS. 2 (1):1-5.
Wongwiwattana, J., 2002. Synthesis and Kinetic Study of Zeolite Na-A From Thai Kaolin. Thailand : Suranaree University of Technology.
Yunita, I., 2008. Pengaruh Waktu Reaksi Pada Sintesis Zeolit Dari Abu Sekam Padi Serta Aplikasinya Sebagai Penukar Ion. Tugas Akhir 2. Semarang: Jurusan Kimia FMIPA UNNES.
Zhang, X., Tang, D., Zhang, M. dan Yang, R., 2013. Synthesis Of Nax Zeolite: Influence Of Crystallization Time, Temperature And Batch Molar Ratio SiO2/Al2O3 On The Particulate Properties Of Zeolite Crystals. Powder Technology 235: 322–328
Zhao, Y., Zhang, B., Zhang, X., Liu, J. dan Chen, R., 2010. Ammonium Removal from Aquoeous Solution by Zeolite X Synthesized from Halloysite Mineral. Water Science & Technology. 62 (4): 937-946.
Zhely, M. N. H. dan Widiastuti N., 2012. Sintesis Zeolit X-karbon dari Abu Dasar Batubara dan Karakterisasinya sebagai Material Penyimpan Hidrogen. Prosiding KIMIA FMIPA – ITS.
Zhou, W. dan Wang, Z.L., 2006. Scanning Microscopy for Nanotechnology. Library of Congress Control Number: 2006925865.
Zhou, Z., Jin, G., Liu, H., Wu, J. dan Mei, J., 2014. Crystallization Mechanism of Zeolite A from Coal Kaolin Using A Two-step Method. Applied Clay Science 97–98: 110–114.
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Affiliations
Amir Setiadi
Affiliation not stated
How to Cite
Setiadi, A. (2017). SINTESIS ZEOLIT DENGAN KANDUNGAN Si/Al RENDAH DARI KAOLIN MENGGUNAKAN METODE PELEBURAN DAN HIDROTERMAL. Indonesian Journal of Chemical Science, 5(3), 164-168. https://doi.org/10.15294/ijcs.v5i3.9325
SINTESIS ZEOLIT DENGAN KANDUNGAN Si/Al RENDAH DARI KAOLIN MENGGUNAKAN METODE PELEBURAN DAN HIDROTERMAL
Abstract
Kaolin contains silicon 42,3% and aluminium 24% therefore it is potential as basic material for zeolite synthesis process. Zeolite can be synthesized from material which contains Si and Al. In this study it synthesized zeolite from kaolin using fusion and hidrotermal method. Kaolin was mixed with NaOH powder as mineralizer. Fusion method was carried out on temperature of 450°C for 2 hours then followed by hidrothermal method which was carried out on 175°C for 6 hours. Pro analyst NaOH and technical NaOH were used in this research. This aimed to distinguish the synthesized zeolites from two types of NaOH. The mixing of NaOH powder/kaolin (w/w) is variated respectively 0,5; 1; 1,25; and 1,5. Characterizations of synthesized zeolite were performed by using XRD, FTIR, and SEM. Characterization result showed that zeolite with technical NaOH/kaolin ratio=1,25 producing percentage of zeolite A (LTA) relative intensity 37,54% and percentage of crystallinity 91,42%. Zeolite with pro analyst NaOH/kaolin ratio=1 producing percentage of zeolite A (LTA) relative intensity 22,72% and percentage of crystallinity 85,37%. This research showed that based on qualitative aspect, pro analyst NaOH is better as mineralizer in synthesize of zeolite A signed by more peaks, while based on quantitative aspect, technical NaOH is better as mineralizer signed by high crystallinity and pecentage relative intensity value.