Characterization of Liquid Smoke from Dried Water Hyacinth Using GCMS (Gas Chromatography-Mass Spectrophotometry) to Utilize Weeds as Food Preservative

R. D. Ratnani, H. Hadiyanto, W. Widiyanto, M. A. Adhi

Abstract

Water hyacinth is a weed in Rawa Pening because of its rapid growth. A handling effort is a very crucial thing and must be done immediately. This study aims to characterize organic compounds in liquid smoke from dried water hyacinth. ­­­­Characterization of organic compounds from dried water hyacinth was carried out on water hyacinth liquid smoke which was pyrolyzed at 200°C and 600°C. Pyrolysis times were run at 2 hours and 6 hours. Liquid smoke from dried water hyacinth was distilled before testing its chemical composition using GCMS brand Shimadzu type QP 2010S. The results of liquid smoke characterization are used to decide that liquid smoke can be utilized as a food preservative. The test results report that the liquid smoke produced had an acid percentage ranging from 29.63% to 37.23%, phenol from 1.04 to 6.11%, and the remaining carbonyl compounds from 55.99% to 68.90%. The highest component value was obtained at 600°C pyrolysis and 6 hours. The conclusion is that liquid smoke from dried water hyacinth can be used as a food preservative because it contains acid, phenol, and carbonyl and is free of Benzo (a) pyrene, which can cause cancer. So that the requirement for liquid smoke as a preservative can be achieved, whereas acid is a food preservative. This study generates the acquisition of natural food preservatives to utilize weeds. The research helps us utilize weeds to resist the Rawa Pening environment and manufacture food preservatives.

Keywords

liquid smoke; organic compound; total acid; total phenol; water hyacinth

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References

Alvarez, J., Amutio, M., Lopez, G., Santamaria, L., Bilbao, J., & Olazar, M. (2019). Improving Bio-oil Properties Through the Fast Co-pyrolysis of Lignocellulosic Biomass and Waste Tyres. Waste Management, 85, 385–395.

Bote, M. A., Naik, V. R., & Jagadeeshgouda, K. B. (2020). Materials Science for Energy Technologies Review on Water Hyacinth Weed as a Potential Bio Fuel Crop to Meet Collective Energy Needs. Materials Science for Energy Technologies, 3, 397–406.

Chowdhury, Z. Z., Pal, K., Yehye, W., & Suresh, S. (2017). Pyrolysis : A Sustainable Way to Generate Energy from Waste. In World’s largest Science, Technology & Medicine Open Access book publisher (pp. 1–36).

David, E., & Kopac, J. (2018). Pyrolysis of Rapeseed Oil Cake in a Fixed Bed Reactor to Produce Bio-oil. Journal of Analytical and Applied Pyrolysis, 134, 495–502.

Desniorita, D., & Maryam, M. (2015). The effect of Adding Liquid Smoke Powder to Shelf Life of Sauce. International Journal on Advanced Science, Engineering and Information Technology, 5(6), 457–459.

Desvita, H., Faisal, M., Mahidin, & Suhendrayatna. (2020). Preservation of Meatballs with Edible Coating of Chitosan Dissolved in Rice Hull-Based Liquid Smoke. Heliyon, 6(10), 1–6.

Dina, R. A., Pangestuti, D. R., & Fahmi, A. S. (2017). Design of Liquid Smoke Pyrolysis on Red Brick Burning in ‘Smoke Village’ (Case Study of Kalipucang Kulon Village-Jepara District). International Journal of Sciences: Basic and Applied Research (IJSBAR), 36(6), 95–104.

Eid, E. M., & Shaltout, K. H. (2017). Growth Dynamics of Water Hyacinth (Eichhornia crassipes): a Modeling Approach. Rendiconti Lincei. Scienze Fisiche e Naturali, 28(1), 169–181.

Gonz, S., Manj, L., & Peinado, M. (2020). Composition, Ageing and Herbicidal Properties of Wood Vinegar Obtained Through Fast Biomass Pyrolysis. Energies, 13, 1–17.

Essumang, D. K., Dodoo, D. K., & Adjei, J. K. (2012). Polycyclic Aromatic Hydrocarbon ( PAH ) Contamination in Smoke-Cured Fish Products. Journal of Food Composition and Analysis, 27, 128–138.

Faisal, M., Yelviasunarti, A. R., & Desvita, H. (2018). Characteristics of Liquid Smoke From the Pyrolysis of Durian Peel Waste at Moderate Temperatures. Rasayan Journal Chemical, 11(2), 871–876.

Guo, W., Yang, Q., Sun, Y., Xu, S., Kang, S., Lai, C., & Guo, M. (2020). Characteristics of Low-Temperature Co-current Oxidizing Pyrolysis of Huadian Oil Shale. Journal of Analytical and Applied Pyrolysis, 146(2020), 104759.

Hadanu, R., Ambrosius, D., & Apituley, N. (2016). Volatile Compounds Detected in Coconut Shell Liquid Smoke through Pyrolysis at a Fractioning Temperature of 350-420 °C. Makara Journal of Science, 20(3), 95–100.

Hashem, A., Hasan, M., Momen, A., Payel, S., Tomal, S., & et al. (2020). Water Hyacinth Biochar for Trivalent Chromium Adsorption from Tannery Wastewater. Environmental and Sustainability Indicators, 5(2020), 1–6.

Huang, Y., Li, S., Chen, J., Zhang, X., & Chen, Y. (2014). Adsorption of Pb (II) on Mesoporous Activated Carbons Fabricated from Water Hyacinth using H3PO4 Activation: Adsorption Capacity, Kinetic and Isotherm studies. Applied Surface Science, 293, 160–168.

Indiarto, R., Nurhadi, B., Tensiska, Subroto, E., & Istiqamah, Y. J. (2020). Effect of Liquid Smoke on Microbiological and Physico-Chemical Properties of Beef Meatballs During Storage. Food Research.

Istirokhatun, T., Rokhati, N., Rachmawaty, R., Meriyani, M., Priyanto, S., & Susanto, H. (2015). Cellulose Isolation from Tropical Water Hyacinth for Membrane Preparation. Procedia Environmental Sciences, 23, 274–281.

Janairo, J. I. B., & Amalin, D. M. (2018). Volatile Chemical Profile of Cacao Liquid Smoke. International Food Research Journal, 25, 213–216.

Kailaku, S., Syakir, M., Mulyawanti, I., & Syah, A. (2017). Antimicrobial Activity of Coconut Shell Liquid Smoke. In Materials Science and Engineering (pp. 1–7).

Keryanti, Permanasari, A. R., Yulistiani, F., Sihombing, R. P., & Wibisono, W. (2020). Applications of Liquid Smoke from Biomass on Food Products: A Review. In International Seminar of Science and Applied Technology (ISSAT 2020) (Vol. 198, pp. 518-524 [In Indonesia]).

Kumar, M., Mishra, P. K., & Upadhyay, S. N. (2019). Pyrolysis of Saccharum Munja: Optimization of Process Parameters using Response Surface Methodology (RSM) and Evaluation of Kinetic Parameters. Bioresource Technology Reports Journal, 8, 1–11.

Ledesma, B., Alvarez, A., Rom, S., Coronella, C., & Qaramaleki, S. V. (2020). Suitability of Hydrothermal Carbonization to Convert Water Hyacinth to Added-Value Products. Renewable Energy Journal, 146, 1649–1658.

Lin, H., Rong, C., Jiu, B., Li, B., Yu, Q., Gan, L., & Zhang, Z. (2018). Effects of Chromium on Pyrolysis Characteristic of Water Hyacinth (Eichornia crassipes). Renewable Energy, 115, 676–684.

Liu, C., Ye, J., Lin, Y., Wu, J., Price, G. W., Burton, D., & Wang, Y. (2020). Removal of Cadmium (II) using Water Hyacinth (Eichhornia crassipes) Biochar Alginate Beads in Aqueous Solutions. Environmental Pollution, 264, 114785.

Ma, H., Li, T., Wu, S., & Zhang, X. (2020). Effect of the Interaction of Phenolic Hydroxyl with the Benzene Rings on Lignin Pyrolysis. Bioresource Technology, 309, 123351.

Martínez, O., Salmeron, J., Epelde, L., Vicente, M. S., & Vega, C. de. (2018). Quality Enhancement of Smoked Sea Bass (Dicentrarchus labrax) Fillets by Adding Resveratrol and Coating with Chitosan and Alginate Edible Films. Food Control, 85, 168–176.

Mishra, R. K., & Mohanty, K. (2018). Thermocatalytic Conversion of Non-edible Neem Seeds Towards Clean Fuel and Chemicals. Journal of Analytical and Applied Pyrolysis, 134, 83–92.

Mukarugwiro, J. A., Newete, S. W., Adam, E., Nsanganwimana, F., Abutaleb, K., & Byrne, M. J. (2021). Mapping Spatio-Temporal Variations in Water Hyacinth (Eichhornia crassipes) Coverage on Rwandan Water Bodies using Multispectral Imageries. International Journal of Environmental Science and Technology, 18(2), 275–286.

Nithin C.T., Joshya, C. G., Chatterjeea, N. S., Panda, S. K., Yathavamoorthi, R., Ananthanarayanan, T. R., & Gopal, T. K. S. (2020). Liquid Smoking - A safe and Convenient Alternative for Traditional Fish Smoked Products. Food Control, 113(1), 107186.

Niu, Y., Lv, Y., Lei, Y., Liu, S., Liang, Y., Wang, D., & Hui, S. (2019). Biomass torrefaction : Properties, Applications, Challenges, and Economy. Renewable and Sustainable Energy Reviews, 115, 109395.

Prasetyo, S., Anggoro, S., & Soeprobowati, T. R. (2021). The Growth Rate of Water Hyacinth (Eichhornia Crassipes (Mart.) Solms) in Rawapening Lake, Central Java. Journal of Ecological Engineering, 22(6), 222–231.

Pratiwi, F. D., Zainuri, M., Purnomo, P. W., & Purwati, F. (2018). Stakeholder Perception and Participation in Relation to Success Rate of Water Hyacinth Control Program in the Rawa Pening Lake. AACL Bioflux, 11(4), 967–979.

Purwanto, P., Retnowati, R., & Suryanto, H. (2020). Strategy for Enhancing Community Economy Through Optimization of Tourism Areas (A Study on Rawa Pening Lakes in Central Java Province - Indonesia). Journal of International Conference Proceedings, 3(1), 183–193.

Ratnani, R. D., Hadiyanto, H., & Widiyanto, W. (2021). Effect of Temperature and Pyrolysis Time in Liquid Smoke Production from Dried Water Hyacinth. Journal of Environmental Treatment Techniques, 9(1), 164–171.

Ratnani, R. D., & Widiyanto. (2018). A Review of Pyrolisis of Eceng Gondok (Water hyacinth) for Liquid Smoke. E3S Web of Conferences, 73, 2–6.

Sagar, C. V., & Kumari, N. A. (2013). Sustainable Biofuel Production From Water Hyacinth (Eicchornia Crassipes). International Journal of Engineering Trend and Technology (IJETT), 4(10), 4454–4458.

Saldaña, E., Saldarriaga, L., Cabrera, J., Siche, R., Aurélio, M., Almeida, D., Behrens, J. H., Mabel, M., & Contreras-castillo, C. J. (2018). Descriptive Analysis of Bacon Smoked with Brazilian Woods from Reforestation : Methodological Aspects, Statistical Analysis, and Study of Sensory characteristics. Meat Science, 140, 44–50.

Saldaña, E., Soletti, I., Marinho, M., Schmidt, B., Cardoso, T., Mabel, M., Clara, A., Teixeira, B., Gomes, F., & Contreras-castillo, C. J. (2019). Understanding Consumers ’ Dynamic Sensory Perception for Bacon Smoked with Different Brazilian Woods. Meat Science, 154(April), 46–53.

Sarto, S., Hildayati, R., & Syaichurrozi, I. (2019). Effect of Chemical Pretreatment using Sulfuric Acid on Biogas Production from Water Hyacinth and Kinetics. Renewable Energy, 132, 335–350.

Sokamte, T. A., Mbougueng, P. D., Sachindra, N. M., Douanla, N. F. N., & Tatsadjieu, N. L. (2020). Characterization of Volatile Compounds of Liquid Smoke Flavourings from Some Tropical Hardwoods. Scientific African, 20, 1–37.

Solikhah, M. D., Pratiwi, F. T., Sutrisno, B., & Hidayat, A. (2017). Formation, Analysis, and Characterization of Wood Pyrolyzed Oil. Materials Science and Engineering, 1–7.

Suryanto, H., Retnowati, R., & Purwanto, P. (2020). Local Wisdom Management to Maintain the Local Environment (A Study of the Naga Baru Klinting folklore in Rawa Pening Ambarawa). Journal of International Conference Proceedings, 3(1), 116–123.

Su, W., Sun, Q., Xia, M., Wen, S., & Yao, Z. (2018). The Resource Utilization of Water Hyacinth (Eichhornia crassipes [Mart.] Solms) and Its Challenges. Resources, 7(46), 910.

Sulhatun, S., Hasibuani, R., & Harahap, H. (2019). Influence Temperatur of Pyrolisis Process on Production of Liquid Smoke from Candlenut Shell by Examining its Potential Compound. International Journal of Recent Technology and Engineeringngineering, 8(3), 285–290.

Sun, D., Onyianta, A. J., Rourke, D. O., Perrin, G., Popescu, C., Saw, L. H., Cai, Z., & Dorris, M. (2020). A Process for Deriving High-Quality Cellulose Nanofibrils from Water Hyacinth Invasive Species. Cellulose, 27, 3727–3740.

Swastawati, F., Boesono, H., Susanto, E., & Indah, A. (2016). Changes of Amino Acids and Quality in Smoked Milkfish [ Chanos chanos (Forskal 1775 )] Processed by Different Redestilation Methods of Corncob Liquid Smoke. Aquatic Procedia, 7, 100–105.

Swastawati, F., Darmanto, Y. S., Sya, L., Kuswanto, K. R., & Taylor, K. D. A. (2014). Quality Characteristics of Smoked Skipjack (Katsuwonuspelamis) Using Different Liquid Smoke. International Journal of Bioscience, Biochemistry, and Bioinformatics, 4(2), 94–99.

Tran, T. K., Kim, N., Leu, H. J., Pham, M. P., Luong, N. A., & Vo, H. K. (2021). The Production of Hydrogen Gas from Modified Water Hyacinth (Eichhornia Crassipes) Biomass Through Pyrolysis Process. International Journal of Hydrogen Energy, 46, 13976–13984.

Tsekos, C., Anastasakis, K., Schoenmakers, P. L., & Jong, W. De. (2020). PAH Sampling and Quantification from Woody Biomass Fast Pyrolysis in a Pyroprobe Reactor with a Modified Tar Sampling System. Journal of Analytical and Applied Pyrolysis, 147(February), 104802.

Usino, D. O., Ylitervo, P., Pettersson, A., & Richards, T. (2020). Influence of Temperature and Time on Initial Pyrolysis of Cellulose and Xylan. Journal of Analytical and Applied Pyrolysis, 147(January), 104782.

Venu, H., Venkataraman, D., Purushothaman, P., & Vallapudi, D. R. (2019). Eichhornia Crassipes Biodiesel As a Renewable Green Fuel for Diesel Engine Applications : Performance, Combustion, and Emission Characteristics. Environmental Science and Pollution Research, 26, 18084–18097.

Vinicius, C., Rigueto, T., Stefanello, J., Dettmer, A., Rosseto, M., Luiz, G., Paula, A., Schmitz, D. O., Perondi, D., Stéphanie, T., Freitas, M. De, & Aparecida, R. (2020). Water Hyacinth (Eichhornia crassipes) Roots, An Amazon Natural Waste, as an Alternative Biosorbent to Uptake a Reactive Textile Dye from Aqueous Solutions. Ecological Engineering, 150, 105817.

Wijayanti, I., Swastawati, F., Ambariyanto, Cahyono, B., & Chilmawati, D. (2020). Application of Filtration and Re-distillation of Liquid Smoke as Flavouring Agent on Texture, Proximate and Sensory Characteristics of Milkfish (Chanos chanos) Fishballs. African Journal of Food Agriculture Nutrition and Development, 20(2), 15569–15581.

Wu, P., Zhang, X., Wang, J., Yang, J., Peng, X., Feng, L., Zu, B., Xie, Y., & Li, M. (2021). Pyrolysis of Aquatic Fern and Macroalgae Biomass into Bio-oil : Comparison and Optimization of Operational Parameters using Response Surface Methodology. Journal of the Energy Institute Journal, 97, 194–202.

Yao, Z., Ma, X., & Xiao, Z. (2020). The Effect of Two Pretreatment Levels on the Pyrolysis Characteristics of Water Hyacinth. Renewable Energy, 151, 514–527.

Yin, L., Leng, E., Fang, Y., Liu, T., Gong, X., & Zhou, J. (2020). Effects of KCl, KOH, and K2CO3 on the Pyrolysis of Cβ-O type Lignin-Related Polymers. Journal of Analytical and Applied Pyrolysis, 147(12), 104809.

Zachara, A., Gałkowska, D., & Juszczak, L. (2017). Contamination of Smoked Meat and Fish Products from Polish Market with Polycyclic Aromatic Hydrocarbons. Food Control, 80, 45–51.

Zhang, B., Zhong, Z., Li, T., Xue, Z., & Ruan, R. (2018). Bio-oil Production from Sequential Two-step Microwave-assisted Catalytic Fast Pyrolysis of Water Hyacinth using Ce-doped γ -Al2O3/ZrO2 Composite Mesoporous Catalyst. Journal of Analytical and Applied Pyrolysis, 132, 143–150.

Zhang, L., Bao, Z., Xia, S., & Lu, Q. (2018). Catalytic Pyrolysis of Biomass and Polymer Wastes. Catalysts, 8(659), 1–45.

Zheng, S., Yang, Y., Li, X., Liu, H., Yan, W., Sui, R., & Lu, Q. (2020). Temperature and Emissivity Measurements from Combustion of Pine Wood, Rice Husk, and Fir Wood Using Flame Emission Spectrum. Fuel Processing Technology, 204(March), 106423.

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