DESIGN OF THERMAL EQUIPMENT MILLING FOR FABRICATING THE TIO2 PHOTOCATALYSTS COATED GRAIN POLYMERS
(1) Physics Department, Faculty of Sciences and Technology State Islamic University of Sunan Gunung Jati Bandung, Indonesia Jl. A. H. Nasution 105 Bandung
(2) Physics Program, Faculty of Mathematics and Natural Sciences Education Indonesia University of Education, Bandung, Indonesia Jl. Dr. Setiabudhi 229 Bandung
(3) Physics Program, Faculty of Mathematics and Natural Sciences Education Universitas Negeri Semarang, Indonesia Kampus Sekaran Gunungpati Semarang 50229
(4) Physics Program, Faculty of Mathematics and Natural Sciences Bandung Institute of Technology Bandung, Bandung, Indonesia Jl. Ganesha No. 5 Bandung
Abstract
Organic waste water treatment can be conducted with technique of photocatalytic. Photocatalytic activity involves factors light intensity and amount of catalyst. In order this process can take place optimally, the catalyst material coating on the surface of the material buffer such as polymer shaped grains can be an alternative method. Setting the temperature and the duration of heating automatically is very efficient in controlling the physical characteristics of the photocatalyst materials. In this experiment, modification done on of the two types of thermal equipment milling namely cylindrical equipment milling equipped with heater and equipment milling based electric oven. The testing process of the thermal equipment milling performed with controlled temperature in the range of 110 ° C and setting the timer to 60 minutes. In testing the thermal characteristics of milling equipment, it takes as long as 220 minutes for each immobilization process using cylindrical milling and 65 minutes when using an electric oven. Setting the temperature and time in the electric oven milling can be performed automatically, which can not be performed using cylindrical milling. Milling equipment based electric oven has also been used in the selection of buffer polymer materials and fabricate TiO2 photocatalysts which tested on photodegradation of organic compound of methylene blue (MB).
Penjernihan air limbah organik dapat dilakukan dengan teknik fotokatalisis. Agar aktivitas fotokatalitik yang melibatkan faktor intensitas cahaya dan jumlah katalis dapat berlangsung secara optimal, pelapisan material katalis pada permukaan material penyangga berupa bulir polimer termoplastik dapat menjadi salah satu alternatif. Pengaturan temperatur dan lamanya pemanasan secara otomatis sangat efisien dalam mengendalikan karakteristik fisis material fotokatalis Dalam penelitian ini dilakukan modifikasi terhadap dua jenis peralatan thermal millng, yaitu peralatan milling cylinder yang dilengkapi dengan komponen pemanas dan peralatan miling berbasis oven listrik. Proses pengujian milling dilakukan dengan temperatur terkontrol pada kisaran 110 °C dan pengaturan timer 60 menit. Dalam pengujiankarakteristik termal kedua alat tersebut, dibutuhkan waktu selama 220 menit untuk setiap proses imobilisasi menggunakan milling cylinder dan 65 menit bila menggunakan peralatan berbasis oven listrik. Pengaturan temperatur dan waktu pada alat berbasis oven listrik dapat dilakukan secara otomatis, yang tidak dapat dilakukan menggunak milling cylinder. Peralatan milling berbasis oven listrik ini juga telah digunakan dalam pemilihan polimer penyangga material fotokatalis TiO2 serta pabrikasi fotokatalis TiO2 yang diujikan dalam fotodegradasi senyawa organik metilen biru (MB).
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Aliah, H. (2012). Imobilisasi, TiO2 pada Permukaan Bulir Polimer Polipropilena dan Aplikasinya sebagai Fotokatalis pada Fotodegradasi Metilen Biru, (Unpublished, doctoral disertation), ITB, Bandung, Indonesia.
Aliah, H., Aji, M. P., Masturi, Sustini, E., Budiman, M., dan Abdullah, M., (2012). The TiO2 Nanoparticles-Coated Polypropylene Copolymer as Photocatalyst on Methylene Blue Photodegradation under Solar Exposure, Am. J. Environ. Sci., 8(3), 280-290.
Aliah, H., Setiawan, A., Masturi, Abdullah, M. (2014). Pemilihan Jenis Bulir Polimer sebagai Penyangga Material Fotokatalis TiO2, Jurnal Fisika, Vol. 4 No.1.
Amalia, I. F., Aliah, H., Khairurrijal, dan Abdullah, M. (2011). Optimasi Jumlah Katalis TiO2 pada Fotodegradasi Larutan Metilen Biru dengan Matahari sebagai Sumber Cahaya, Prosiding Seminar Nasional Penelitian, Pendidikan dan Penerapan MIPA, Fakultas MIPA, Universitas Negeri Yogyakarta.
Arutanti, O, Abdullah, M. (2009). Penjernihan Air Dari Pencemar Organik dengan Proses Fotokatalis pada Permukaan Titanium Dioksida (TiO2), J. Nano Saintek. Spec. Ed.Agust, 43-45.
Borchate, S. S., Kulkarni, G. S., Kore, S. V., Kore, V. S. (2012). Application of Coagulation Flocculation for Vegetable Tannery Wastewater, International Journal of Engineering Science and Technology, 4 (5), 1944-1948.
Fujishima, A., Rao, T. N., Tryk, D. A. (2000). Titanium dioxide photocatalysis, Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 1, 1–21.
Harush, D. P., Hampannavar, U. S., Mallikarjunaswami, M. E. (2011). Treatment of Dairy Wastewater using Aerobic Biodegradation and Coagulation, International Journal of Environmental Sciences and Research, 1(1), 23-26.
Isnaini, V.A., Arutanti, O., Sustini, E., Aliah, H., Khairurrijal dan Abdullah, M. (2011). A Novel System for Producing Photocatalytic Titanium Dioxide Coated Fibers for Decomposing Organic Pollutants in Water, Environ. Prog. Sustainable. Energy.
Liang, H., Gong, W., Li, G. (2008). Performance Evaluation of Water Treatment Ultrafiltration Pilot Plants Treating Algae-rich Reservoir Water, Desalination, 221, 345–350.
Lotfy, H. R., Misihairabgwi, J., dan Mutwa, M. M. (2012). The Preparation of Ativated Carbon from Agroforestry Waste for Wastewater Treatment, African Journal of Pure and Applied Chemistry, 6(11), 149-156.
Mahne, D., Stangar, U. L., Trebse, P., Bulc, T. G. (2012). TiO2-Based Photocatalytic Treatment of Raw and Constructed-Wetland Pretreated Textile Wastewater, International Journal of Photoenergy, Vol. 2012.
Moghaddam, M. B. and Yangjeh, A. H. (2011). Effect of Operational Parameters on Photodegradation of Methylene Blue on ZnS Nanoparticles Prepared in Presence of An Ionic Liquid as A Highly Efficient Photocatalyst, J. Iran. Chem. Soc., Vol. 8, 169-175.
Rajeswari, R., Kanmani, S. (2009): TiO2-Based Heterogeneous Photocatalytic Treatment Combined With Ozonation for Carbendazim Degradation, Iran J. Environ. Health. Sci. Eng., Vol. 6, No. 2, 61-66.
Rashed, M. N., El-Amin, A. A. (2007): Photocatalytic Degradation of Methyl Orange in Aqueous TiO2 Under Different Solar Irradiation Sources, Int. J. Phys. Sci., Vol. 2, No. 3, 073-081.
Qin, J. J., Liberman, B., Kekre, K. A. (2009). Direct Osmosis for Reverse Osmosis Fouling Control: Principles, Applications and Recent Developments, The Open Chemical Engineering Journal, 3, 8-16.
Sala, M., dan Bouz´an, M. C. G. (2012). Electrochemical Techniques in Textile Processes and Wastewater Treatment, International Journal of Photoenergy, Vol. 2012, Article ID 629103.
Siddique, M., Farooq, R., Shaheen, A. (2011). Removal of Reactive Blue 19 from Wastewaters by Physicochemical and Biological Processes-A Review, J.Chem.Soc.Pak., 33(2).
Zahraa, O., Maire, S. Evenou, F., Hachem, C., Pons, M. N., Alinsafi, A., Bouchy, N. (2006). Treatment of Wastewater Dyeing Agent by Photocatalytic Process in Solar Reactor, Int. J. of Photoenergy, Vol. 2006, 1–9.
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